Which of the following alcohol is oxidized to a ketone by chromic acid?

Chromic acid oxidizes primary alcohols to carboxylic acids, and it oxidizes secondary alcohols to ketones.

Which of the following alcohols can be oxidized to a ketone?

Primary alcohols can be oxidized to form aldehydes and carboxylic acids; secondary alcohols can be oxidized to give ketones. Tertiary alcohols, in contrast, cannot be oxidized without breaking the molecule’s C–C bonds.

Which compound is oxidized to a ketone by chromic acid?

Ketones are not oxidized by chromic acid, so the reaction stops at the ketone stage. In contrast, primary alcohols are oxidized by chromic acid first to aldehydes, then straight on to carboxylic acids.

Which can be oxidized by chromic acid?

Chromic acid (H2CrO4) oxidizes alcohols in aqueous solutions of sodium dichromate. It reacts with alcohols to form a chromic ester in which the alcohol oxygen atom bridges the carbon and chromium atoms. … In an aqueous acid solution, chromic acid converts aldehydes to carboxylic acids.

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Can 2 propanone be oxidized?

The oxidation of the simplest secondary alcohol, 2-propanol, yields propanone. Tertiary alcohols cannot be oxidized in this way because the carbon to which the hydroxyl group is attached does not have another hydrogen atom attached to it.

Which alcohol can be oxidised by K2Cr2O7 and h2so4 to form a ketone?

Secondary alcohols are oxidised to ketones – and that’s it. For example, if you heat the secondary alcohol propan-2-ol with sodium or potassium dichromate(VI) solution acidified with dilute sulphuric acid, you get propanone formed.

What product would I obtain if I treat a primary alcohol with chromic acid?

Once H2CrO4 is formed, its reactions are pretty straightforward: it converts primary alcohols (and aldehydes) to carboxylic acids and secondary alcohols to ketones.

What happens when phenol is oxidised with chromic acid?

Answer. Phenols are rather easily oxidized despite the absence of a hydrogen atom on the hydroxyl bearing carbon. Among the colored products from the oxidation of phenol by chromic acid is the dicarbonyl compound para-benzoquinone (also known as 1,4-benzoquinone or simply quinone); an ortho isomer is also known.

What happens when a ketone is oxidized?

Ketone oxidation implies the rupture of a C-C bond. If it is energic (KMnO4, K2Cr2O7) two carboxylic groups will be produced. If it is smooth (Baeyer-Villiger oxidation), an ester is produced that, once it is hydrolized, gives rise to a carboxylic acid and an alcohol.

Can Acetone be oxidized?

Oxidation of acetone is very difficult; even agents like KMnO4 will not oxidize it. The reason is because oxidation of acetone requires the destruction of the carbon skeleton of the acetone molecule.

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What is the formula of chromic acid?

H2CrO4

Why is acetone used in oxidation?

Acetone not only helps in the dissolution of the substrate but also prevents epimerization by acid-catalyzed enolization of the α-center in the ketones during oxidation of the secondary alcohols.

What converts an alcohol to a ketone?

A secondary alcohol can be oxidised into a ketone using acidified potassium dichromate and heating under reflux.

Which alcohol can form a ketone?

Secondary alcohols are oxidised to ketones. There is no further reaction which might complicate things. For example, if you heat the secondary alcohol propan-2-ol with sodium or potassium dichromate(VI) solution acidified with dilute sulphuric acid, you get propanone formed.

What type of alcohol is resistant to oxidation?

Tertiary alcohols (R3COH) are resistant to oxidation because the carbon atom that carries the OH group does not have a hydrogen atom attached but is instead bonded to other carbon atoms.

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